Department of Earth and Atmospheric Sciences, Cornell University, Ithaca, NY 14853, USA

now at: Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139, USA

Department of Earth and Atmospheric Sciences, Cornell University, Ithaca, NY 14853, USA

Climate and Global Dynamics Division, National Center for Atmospheric Research, Boulder, CO 80305, USA

Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, MA 02543, USA

Department of Earth System Science, University of California, Irvine, CA 92697, USA

Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA